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Question

A gas expands adiabatically from 1.0 L to 12.0 L against a constant pressure of 0.75 atm. The â–³U of the gas is

A
- 835.9 J
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B
853.9 J
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C
859.9 J
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D
- 839.5 J
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Solution

The correct option is A - 835.9 J
First law of thermodynamics U=Q+W
Q=0 (adibatic expansion)
so, U=W
U=W=pextV=(0.75 atm)(12.0 L1.0 L)
=8.25 L atm
(8.25 L atm)(8.314 J0.082 Latm)=835.9 J

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