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Question

A gas obeys P(V−b)=RT. Which of the following are correct about this gas?

A
Isochoric curves have slope =RVb
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B
Isochoric curves have slope =RP and intercept b
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C
For the gas compressibility factor =1+PbRT
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D
The attraction forces are overcome by repulsive forces
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Solution

The correct options are
B Isochoric curves have slope =RVb
C The attraction forces are overcome by repulsive forces
D For the gas compressibility factor =1+PbRT
As we know,
Z (compressibility factor) =PV/RT=1+Pb/RT and as Z>1 so attraction forces are overcome by repulsive forces.
And according to a given gas equation,
P and T curve have slope =RVb.

Hence, the correct options are A, C and D

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