A gas obeys P(V−b)=RT. Which of the following are correct about this gas?
A
Isochoric curves have slope =RV−b
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B
Isochoric curves have slope =RP and intercept b
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C
For the gas compressibility factor =1+PbRT
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D
The attraction forces are overcome by repulsive forces
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Solution
The correct options are B Isochoric curves have slope =RV−b C The attraction forces are overcome by repulsive forces D For the gas compressibility factor =1+PbRT As we know, Z (compressibility factor) =PV/RT=1+Pb/RT and as Z>1 so attraction forces are overcome by repulsive forces. And according to a given gas equation, P and T curve have slope =RV−b.