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Question

A gas undergoes a change from state A to state B. In this process, the heat absorbed and work done by the gas is 5 J and 8 J, respectively. Now gas is brought back to A by another process during which 3 J of heat is evolved. In this reverse process of B to A:

A
10 J of the work will be done by the gas.
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B
6 J of the work will be done by the gas.
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C
10 J of the work will be done by the surrounding on gas.
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D
6 J of the work will be done by the surrounding on the gas.
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Solution

The correct option is D 6 J of the work will be done by the surrounding on the gas.
According to the first law of thermodynamics,

ΔU=q+w=58=3 J

As, the internal energy is a state function, for the reverse process ΔU should be equal to 3 J.

ΔU=q+w

+3=3+w

w=+6 J

As work done has a positive sign, work is done by the surrounding on the gas.

Hence, the correct option is D

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