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Question

A gaseous mixture containing 0.35g of N2 and 5600 ml of O2 at STP has kept in a 5 liters at 300K. The total temperature of the gaseous mixture is?

A
1.293 atm
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B
1.2315 atm
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C
12.315 atm
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D
0.616 atm
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Solution

The correct option is B 1.293 atm
Moles of O2=560022400=0.25=nO2
Moles of N2=0.3528=0.0125=nN2
Initial pressure of N2=nN2RTV=0.0125×0.0821×3005=0.061 atm
Potential pressure of O2=nO2RTV=0.25×0.0821×3005=1.231 atm
Total pressure =1.231+0.061=1.292 atm

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