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Question

A gaseous oxide contains 30.4% of nitrogen and one molecule of gas contains two nitrogen atoms. The empirical formula mass of the oxide is _________ g.

A
92
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B
46
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C
108
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D
none of these
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Solution

The correct option is B 46
Nitrogen=30.4%

Oxygen=69.6%

Determine the chemical formula of the oxide
No.of moles of nitrogen=30.414=2.17

No.of moles of oxygen=69.616=4.35

A ratio of moles of nitrogen to oxygen is 2:4=1:2

Hence the formula of the oxide is NO2

Molar mass of the oxide=14+(2×16)=46

Conclusion: hence the option (B) is correct.

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