A glass vessel measures exactly 10 cm × 10 cm × 10 cm at 0∘ C. It is filled completely with mercury at this temperature. When the temperature is raised to 10∘ C, 1.6 cm3 of mercury overflows. Calculate the coefficient of volume expansion of mercury. Coefficient of linear expansion of glass =6.5×10−6 ∘ C−1.
Vg=10×10×10=100 cc.
ΔT=10∘C
V′Hg−V′g=1.6 cm3
αg=6.5×10−6/∘C
γHg=?
γg=3×6.5×10−6/∘C
V′Hg=VHg (1+γHg ΔT) . . . (1)
V′g=Vg(1+γg ΔT) . . . (2)
V′Hg−V′g=VHg−Vg+VHg γHg ΔT−Vg γg ΔT
1.6=1000×γHg×10−1000×6.5×3×10−6×10
γHg=1.6+19.5×10−210000
=1.6+0.19510000=1.79510000
=1.795×10−4
=1.8×10−4/ ∘C