A graph between logt12 and log[A0] for a reaction at 27∘C is given above. From the graph, which of the following statement(s) is/are correct? (t12= Half-life ; [Ao] = Initial concentration)
A
The unit of k (rate constant) is the same as the rate of the reaction
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B
The half-life is directly proportional to [Ao]
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C
The half-life is independent of [Ao]
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D
The slope of the graph between [At] and t is –k
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Solution
The correct options are A The unit of k (rate constant) is the same as the rate of the reaction B The half-life is directly proportional to [Ao] D The slope of the graph between [At] and t is –k The rate of the reaction is independent of the initial concentration of the reactant in a zero order reaction. Hence, the rate constant and the rate of the reaction have the same units.
For a zero order reaction, [At]=[Ao]−kt t12=[Ao]2k ⇒logt12=−log2k+log[Ao]