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Question

A list of species having the formula XZ4 is given below: XeF4, SF4, SiF4, BF4, BrF4, [Cu(NH3)4]2+, [FeCl4]2, [CoCl4]2 and [PtCl4]2. Defining shape on the basis of the location of X and Z atoms, the total number of species having a square planar shape is

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Solution

XeF4, BrF4, [Cu(NH3)4]2+, [PtCl4]2 are square planar
SF4 is sea saw
SiF4, BF4, [FeCl4]2, [CoCl4]2 are tetrahedral
Compound/Ion Magnetic nature of compound
1. [Ni(CO)4] Diamagnetic
2. [NiCl4]2 Paramagnetic
3. [Co(NH3)4Cl2]Cl Diamagnetic
4. Na3[CoF6] Paramagnetic
5. Na2O2 Diamagnetic
6. CsO2 Paramagnetic

So total number of paramagnetic compound is 3.

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