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Question

A mass of 0.65 g of zinc reacts completely with HCl to produce hydrogen gas and a zinc chloride compound. The mass of the chlorine in the compound is 0.71 g, what is the empirical formula of this compound? (At. mass of Zn=65 g/mol)

A
ZnCl
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B
ZnCl2
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C
ZnCl5
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D
ZnCl4
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Solution

The correct option is B ZnCl2
Zn + HCl ZnxCly + H2
Given, mass of zinc in ZnxCly=0.659 g
Mass of chlorine in ZnxCly=0.71 g
No. of moles of zinc =0.6565=0.01 moles
No. of moles of chlorine =0.7235.45=0.02 moles
Ratio of zinc to chlorine =Zn:Cl=1:2
So, empirical formula =ZnCl2

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