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Question

A nitrile X is treated with LiAlH4 to obtain compound Y(C2H7N). In a separate reaction X is hydrolyzed in an acid medium to obtain Z. The product obtained after mixing Y and Z will be?

A
CH3CONHCH2CH3
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B
CH3CH2CONHCH2CH3
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C
(CH3COO)(CH3CH2NH+3)
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D
(CH3CH2COO)(CH3NH+2)
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Solution

The correct option is C (CH3COO)(CH3CH2NH+3)
XLiAlH4−−−−−ReductionC2H7N (Amine =Y)

X is CH3CN (Cyanomethane)
XH+Z
CH3CNH+CH3COOH
Z=CH3COOH

Product after mixing Y and Z is (CH3COO)+(CH3CH2NH+3) (Substituted Ammonium Carboxylate Salt)

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