A photoelectric material having work-function ϕ0 is illuminated with light of wavelength λ (λ<hcϕ0). The fastest photoelectron has a de Broglie wavelength λd. A change in wavelength of the incident light by Δλ results in a change Δλd in λd. Then the ratio Δλd/Δλ is proportional to
λ3dλ2
According to photoelectric equation,
we know that kinetic energy of fastest photoelectron is
hcλ−ϕ0=12mv2=p22m=h22mλ2d
Diffrentiating both sides we get,
−hcλ2×Δλ=−h2mλ3d×Δλd
∴ we get the proportionality of
ΔλdΔλ∝λ3dλ2