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Dehydration of Alcohols

A reaction ha...

Question

A reaction having equal energies of activation for forward and reverse reaction has 1)delta S=0 2)delta H=0 3)delta G =0 4)delta s=delta H=delta G=0

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Solution

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A + B ⟶ 3 C

Δ G = Δ G^{0} + R T

Δ G = Δ H - T Δ S

Δ G = 0

Δ G > 0

I f Δ G < 0

A (s) ⇌ 2 B (g) Δ H^{0} = 160

Δ S^{0} = 400

400

400

A ⇌ P

T_{1}

T_{2}

T_{2} > T_{1}

Δ H^{θ}

Δ S^{θ}

T_{1}

T_{2}

\frac{T_{2}}{T_{1}}

Δ H_{f}^{0}

U B r_{4}

Δ G^{0}

S^{0}

U (s) + 2 B r_{2} (l) \to U B r_{4} (s); Δ G^{0} = - 788.6 K J; S^{0} (J / K - m o l) 50.3, 152.3, 242.6

For a non-spontaneous reaction, at 30 $^{0}$ C, $Δ$ H>0 & $Δ$ S > 0. The reaction becomes spontaneous,elta by

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