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Question

A sample of organic compounds is found to have an optical rotation of +20o. Which of the following statement(s) is/are correct about the sample?

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A
The sample might be a mixture of d-isomers
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B
All compounds in the sample must be containing chiral carbon
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C
The sample might be mixture of d and l isomers in unequal amounts
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D
The compound(s) in the sample must be chiral
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Solution

The correct options are
A The sample might be a mixture of d-isomers
C The sample might be mixture of d and l isomers in unequal amounts
D The compound(s) in the sample must be chiral
As sample has net rotation so it can be pure d compound or a mixture of d compounds or can be mixture of d and l isomers in unequal amounts.

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