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Question

A solution contains 15% glucose [C6H12O6] in water and has density 1.5 g/ml. Find the molarity and molality of this solution [C=12,H=1,O=16].

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Solution

15% glucose C6H12O6 in H2O
15g of glucose in 85g of H2O

Soluteglucose15g

SolventH2O85g

No. of moles of solute=GivenMassMolarMass

Molar Mass of C6H12O6= 6x12+12x1+6x16
= 72+12+96=180
n=15180=0.0833Density1.5g/mL1.5g1mL1g11.5mL100g11.5×100mL1001.5mLofsolution1001.5×11000Lofsolution115LofsolutionMolarity=Moles of soluteVolume of solution in L=15/1801/15=15180×151=1.25MMolality=Moles of soluteMass of solvent in kg=15/18085/1000=15180×100085=5051=0.980m

Molarity of solution=1.25M

Molality of solution=0.980m

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