A solution which is 10−3M each in Mn2+,Fe2+,Zn2+ and Hg2+ is treated with 10−16M sulphide ion. if Ksp of MnS,FeS,ZnS and HgS are 10−15,10−23,10−20 and 10−54 respectively, which one will precipitate first?
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Solution
Sobility product (Ksp) of MnS=10−15
FeS=10−23
ZnS=10−20
HgS=10−54
for precipitation first from the given data, HgS has a KsP of 10−54 which is least. So, HgS precipitates first.