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Question

A solution which is 103M each in Mn2+,Fe2+,Zn2+ and Hg2+ is treated with 1016M sulphide ion. if Ksp of MnS,FeS,ZnS and HgS are 1015,1023,1020 and 1054 respectively, which one will precipitate first?

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Solution

Sobility product (Ksp) of MnS=1015
FeS=1023
ZnS=1020
HgS=1054
for precipitation first from the given data, HgS has a KsP of 1054 which is least. So, HgS precipitates first.

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