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Question

A suspension of CaOCl2 in water is heated with ethanol. The product formed is:

A
ethylene
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B
ethanol
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C
trichloromethane
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D
chloroethane
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Solution

The correct option is C trichloromethane
A suspension of CaOCl2 in water is heated with ethanol. The product formed is trichloromethane.

The reactions are as follows:
CaOCl2+H2OCa(OH)2+Cl2

H2O+Cl2HCl+[O]

CH3CH2OH[O]CH3CHO+H2O

CH3CHO3Cl2−−HClCCl3CHO+H2O

Ca(OH)2+2CCl3CHOΔ2CHCl3Trichloromethane+(HCOO)2Ca

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