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Question

A system in thermodynamic equilibrium will have the maximum value for :

A
Helmholtz free energy
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B
Gibb's free energy
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C
Entropy
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D
Temperature
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Solution

The correct option is C Entropy
A system is said to be in thermodynamic equilibrium when the macroscopic particles do not undergo any change with time.
For a system in thermodynamic equilibrium, S (i.e. entropy) is maximum.

While at constant temperature and volume, A (i.e. Helmholtz free energy) and at constant temperature and pressure, G (i.e. Gibb's free energy) is minimum.

Hence the correct option is C.

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