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Question

A thermally insulated, closed copper vessel contains water at 150C. When the vessel is shaken vigorously for 15 minutes, the temperature rises to 170C. The mass of the vessel is 100 g and that of the water is 200 g. The specific heat capacities of copper and water are 420 J kg1K1 and 4200 J kg1K1 respectively. Neglect any thermal expansion.
(a) How much heat is transferred to the liquid-vessel system?
(b) How much work has been done on this system?
(c) How much is the increase in internal energy of the system?

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Solution

Given data,
t1=150C t2=170C
Δt=t2t1=17C15C=20C=2+273=275K
mv=100g=0.1kg
mw=200g=0.2kg
cug=420J/kgk
Wg=4200J/kgk
a) The heat transferred to the liquid vessel system is 0. The internal heat is shared between the vessel and water.
b) Work done on the system = Heat produced in it.
dw=100×103×420×2+200×103×4200×2
=84+84×20
=84×21=1764J
c) dQ=0,dU=dW=1764J. [since dw=ve work done is converted to heat, So, heat given to liquid is z]

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