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Question

A vessel of volume V = 30 l contains ideal gas at the temperature 0 After a portion of the gas has been let out, the pressure in the vessel decreased by Δp=0.78 atm (the temperature remaining constant). Find the mass of the released gas. The gas density under the normal conditions ρ=1.3g/l

A
30 g
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B
40 g
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C
50 g
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D
None
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Solution

The correct option is A 30 g
If m1 and m2 be the masses of the gas in the vessel before and after the gas is released, then mass of the gas released, Δm=m1m2
Using ideal gas equation, p1V=m1RT0M and p2V=m2RT0M (as V and T are same before and after release of the gas)
Now, (p1p2)V=(m1m2)RT0M
ΔpV=ΔmRT0M
or Δm=MVΔpRT0...(1)
We also know that, p=ρRMT
so , MRT0=ρp0....(2) where p=1atm, standard atmospheric pressure and T0=273K
Using (1) & (2), Δm=ρVΔpp0=1.3×30×0.781=30g

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