i. In steady state, no current will flow through the circuit if S is opened. So the potential at a will be 18 V, and that at b will be zero. Hence, Va−Vb=18−0=18V.
ii. Obviously, a is at the higher potential.
iii. When S is closed, finally in steady state, current I will flow as shown in Figure.
I=186+3=2A,V1=6I=6×2=12V
Vb=18−V1=18−12=6V
iv. q1=C1V1=6×12=72μC
V1+V2=18 or V2=6V,q2=C2V2=3×6=18,μC
Before closing S, the potential on each capacitor is 18 V and charge is q10=6×18=108μC, q20=3×18=54μC
Change in charge is q1−q10=−36μC and q2−q20=−36μC