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Question

A white crystalline solid A on dissolving in water forms a neutral solution. When solid A is heated with calcium hydroxide, it gives off colourless gas B having a sharp biting smell. The gas fumes very strongly in the air and turns red litmus blue. The aqueous solution of A on treating with lead acetate solution forms a white precipitate C. The precipitate is insoluble in all acids.
i) Name the anion present in solid A.
ii) Name the solid A and write its chemical formula.
iii) Name the white precipitate C.
iv) Write one chemical test for the identification of gas B.
v) Name the colourless gas B.

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Solution

B is basic, it turns red to blue litmus.
Pb(OAC)2NH4Cl−−−H2OPbCl2(C)Whiteppt.+NH+4ACO
Test for NH3/NH+4 (Nessler Test)
K2[HgI4]+NH+4OH−− (Millon's base)
(brown ppt.)

1027019_696593_ans_36e84f60f8dd45cf9859d48aaf932a25.PNG

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