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Question

(a) Write balanced equations


(i) when butane is burnt in oxygen
(ii) preparation of ethylene from ethyl alcohol.

(b)

(i)Convert ethane to acetic acid
(ii)Convert acetylene to ethane
(iii)Convert acetic acid to ethyl alcohol
(iv)Convert acetic acid to ethyl acetate.

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Solution

(a)

i) 2 C4H10(g) + 13 O2(g) 8 CO2(g)+ 10 H2O(g)

ii) C2H5OH + conc.H2SO4H2C=CH2 + H2O

(b)

i) CH3CH3+Cl2+sunlight(cat)CH3CH2Cl+aq.KOHCH3CH2OH+alk.KMnO4CH3COOH

ii) Hydrogenation reaction: CHCH+ 2 H2Ni CH3CH3

iii). Reduction reaction: CH3COOHEthanoicacid LiAlH4−−−H2OCH3CH2OHEthanol

iv). O O || || CH3COHAcetic Acid +HOCH2CH3EthanolCH3COCH2CH3Ethyl acetate+H2O


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