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Question

According to molecular orbital theory, the species among the following that does not exist is:

A
He2
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B
He+2
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C
O22
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D
Be2
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Solution

The correct option is D Be2
Electronic configuration of Be2 according to MOT is:
σ1s2σ1s2σ2s2σ2s2
Bond order=NbNa2=442=0
Since the bond order of Be2 molecule is zero, it doesn't exist.

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