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Curtius and Hofmann Rearrangements

Acetaldehyde ...

Question

Acetaldehyde reacts with $P {C l}_{5}$ to give:

C H_{3} C H {C l}_{2}

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C H_{2} - C l | C H_{2} - C l

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C H_{3} C H_{2} C l

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C H {C l}_{2} | C H_{2} C l

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Solution

The correct option is A $C H_{3} C H {C l}_{2}$

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Similar questions

C l - C H_{2} - C H_{3} | C | C H_{3} - C H_{2} - C H_{2} - C l + I^{-} - -- \to D M F

S_{N} 2

K I

C H_{3} - C H_{2} - C H_{2} - C H_{2} - C l a n d C H_{3} - C H ∣ C H_{3} - C H_{2} - C l

(I) (I I)

C H_{3} - C H_{2} - C H_{2} - C l a n d C H_{3} - C H_{2} - C H_{2} - B r

(I) (I I)

C H_{3} - C H ∣ C H_{3} - C H_{2} - C H_{2} - C l a n d C H_{3} - C H_{3} ∣ C ∣ C H_{3} - C H_{2} C l

(I) (I I)

C H_{3} - C H_{2} - C H_{2} - B r ∣ C H - C H_{3} a n d C H_{3} - C H_{3} ∣ C H - C H_{2} - B r ∣ C H - C H_{3}

(I) (I I)

S_{N} 1

C H_{3} - C l | C H | O H - C H_{2} - C H_{2} - C H_{2} - C l

C l - \oplus C H_{2}

F - \oplus C H_{2}

C l - C H_{2} - \oplus C H_{2}

F - C H_{2} - \oplus C H_{2}

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