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Question

Acetylene on treatment with dil.. H2SO4 having HgSO4 gives:

A
Acetaldehyde
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B
Acetic acid
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C
Ethanol
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D
Ethylene
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Solution

The correct option is C Acetaldehyde
In presence of Acid H2SO4 having HgSO4 added into water molecule to the reactant compound. Here reactant compound is Acetylene. So, water will be added to acetylene. This addition is known as Markownikov's addition.
Vinyl alcohol which is obtained by Markownikov's addition undergo tautomerisation and gives acetaldehyde as final product.

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