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Question

Acid rain is due to dissolved non-metallic oxides (SO2,NO2,P2O5,etc.) 10 mL of acid rain sample required 5 mL of 0.01 M Ca(OH)2 for making it neutral. What is the pH of acid rain?
(Write the answer to the nearest interger value)

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Solution

The number of moles of hydroxide ions present in calcium hydroxide is 0.01mol/L×0.005L=5×105mol.
They will neutralize equal number of moles of hydrogen ions.
Hence, the hydrogen ion concentration is 5×105mol0.010L=5×103M
Hence, the pH of the solution is pH=log[H+]=log(5×103)=2.302

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