Although +3 is the characteristic oxidation state for lanthanoids but cerium also shows +4 oxidation state because ___
A
It has variable ionization enthalpy
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B
It has a tendency to attain a noble gas configuration
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C
It has a tendency to attain f0 configuration
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D
It resembles Pb4+
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Solution
The correct options are B It has a tendency to attain a noble gas configuration C It has a tendency to attain f0 configuration There is no simple explanation for this because thermodynamics (as per reduction potentials) suggests that +3 is the more stable one! In its attempt to become Ce, it has a tendency to attain the noble gas configuration. This may further be supported by the stability of the f0 configuration.