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Question

Aluminium carbide reacts with water according to the following equation.
Al4C3+12H2O4Al(OH)3+3CH4
(i) What mass of aluminium hydroxide is formed from 12g of aluminium carbide?
(ii) What volume of methane at s.t.p. is obtained from 12g of aluminium carbide?

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Solution

Molecular weight of Al4C3 is 144 g/mol, Al(OH)3 is 78 g/mol and CH4 is 16 g/mol.
(i)In the reaction:
144 g of Al4C3 gives 312 g Al(OH)3
Therefore 12 g will give 12×312144=26 g Al(OH)3
(ii) 144 g of Al4C3 gives 48 g CH4
Therefore 12 g will give 12×48144=4g CH4
Since 1 mol of gas at STP occupies a volume of 22.4 L
Therefore, volume occupied by 4 g CH4 is:
22.4×416=5.6 L CH4

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