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Chemical Properties of Boron Family

Aluminium chl...

Question

Aluminium chloride exists as a dimer ( $A l_{2} C l_{6}$ ) in solid state as well as in solution of non-polar solvents such as $C_{6} H_{6}$ . When dissolved in water it gives:

A

$A l_{2} O_{3} + 6 H C l$

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B

$[A l (C H_{2} O)_{6}] + 3 C l^{-}$

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C

$[A l (O H)_{6}]^{3 -} + 3 H C l$

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D

$A l^{+ 3} + 3 C l^{-}$

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Solution

The correct option is C
$[A l (O H)_{6}]^{3 -} + 3 H C l$

$A l C l_{3} + 6 H_{2} O \to [A l (O H)_{6}]^{3 -} + 3 H C l$

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