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B
Alumina
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C
Alumina mixed with molten cryolite
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D
Molten cryolite
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Solution
The correct option is D Alumina mixed with molten cryolite
Aluminium is extracted by the electrolysis of purified Al2O3, which is mixed with Na3AlF6 or CaF2, which lowers the melting point of the mixture and brings conductivity. Steel cathode and graphite anode are used. The graphite anode is useful here for reduction to metal. The overall reaction may be taken as:
Al2O3+3C→4Al+3CO2
The process of electrolysis is widely known as the Hall-Heroult process.