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Atomic Size and Electronegativity

Among LiCl , ...

Question

Among $L i C l, B e C l_{2}, B C l_{3}$ and $C C l_{4}$ the covalent bond character follows the order

A

L i C l > B e C l_{2} > B C l_{3} > C C l_{4}

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B

L i C l < B e C l_{2} < B C l_{3} < C C l_{4}

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C

L i C l > B e C l_{2} > C C l_{4} > B C l_{3}

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D

B e C l_{2} > L i C l > B C l_{3} > C C l_{4}

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Solution

The correct option is B $L i C l < B e C l_{2} < B C l_{3} < C C l_{4}$
The electronegativity follows the order: Li<Be<B<C.
The electronegativity difference decreases from left to right in any period, so and hence, the covalent character of chlorides of these elements increase from Li to C.

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Atomic Size and Electronegativity

Standard XII Chemistry

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