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Question

Among the following compounds, the one which can undergo aldol condensation is:

A
(CH3)2CHCHO
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B
HCHO
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C
C6H5CHO
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D
Both (a) and (b)
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Solution

The correct option is A (CH3)2CHCHO
Aldehyde with α hydrogen undergo aldol condensation.
Also, only aldehyde which lacks α hydrogen undergo cannizzaro reaction.
Thus, compound (a) undergoes aldol condensation.
Compound (b) and (c) undergoes cannizzaro reaction.

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