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Chlorides of Phosphorus

Among the fol...

Question

Among the following, the number of compounds that can react with $P C l_{5}$ to give $P O C l_{3}$ is $O_{2}, C O_{2}, S O_{2}, H_{2} O, H_{2} S O_{4}, P_{4} O_{10}$ .___

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Solution

$P C l_{5}$ produces $P O C l_{3}$ with the following reagents:
$P C l_{5} + S O_{2} \to P O C l_{3} + S O C l_{2}$
$P C l_{5} + H_{2} O \to P O C l_{3} + 2 H C l$
$2 P C l_{5} + H_{2} S O_{4} \to S O_{2} C l_{2} + 2 P O C l_{3} + 2 H C l$
$6 P C l_{5} + P_{4} O_{10} \to 10 P O C l_{3}$

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Q. Among the following the number of compounds that can react with

P C l_{5}

P O C l_{3}

O_{2}, C O_{2}, S O_{2}, H_{2} O, H_{2} S O_{4}, P_{4} O_{10}

Q. Among the following, the number of compounds that can react with

P C l_{5}

P O C l_{3}

C_{2} H_{5} O H, S O_{2}, H_{2} O, H_{2} S O_{4}, P_{4} O_{10}

Q. Among the following, choose the compounds that can react with

P C l_{5}

P O C l_{3}

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Q. Among the following, choose the compounds that can react with

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P O C l_{3}

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Q. What weight of each compound will be obtained when

0.450

P_{4} O_{10}

P C l_{5}

are allowed to react completely?
Given reaction:

6 P C l_{5} + P_{4} O_{10} \to 10 P O C l_{3}

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