Among the given cations, the most stable carbonium ion is
A
sec-butyl
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B
tert-butyl
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C
n-butyl
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D
None of these
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Solution
The correct option is B tert-butyl Stability of carbonium ions (carbocations) ∝ Number of α-H
tert-butyl has 9−αH
sec-butyl has 5−αH
n-butyl has 2−αH
Hence the stability order will be: (CH3)3C+>CH3−CH2−+CH−CH3>CH3−CH2−CH2−CH+2