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Question

Among the given cations, the most stable carbonium ion is

A
sec-butyl
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B
tert-butyl
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C
n-butyl
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D
None of these
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Solution

The correct option is B tert-butyl
Stability of carbonium ions (carbocations) Number of α-H
tert-butyl has 9αH
sec-butyl has 5αH
n-butyl has 2αH
Hence the stability order will be:
(CH3)3C+>CH3CH2+CHCH3>CH3CH2CH2CH+2

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