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Question

Among the given reaction which is faster & why?

(i) MeC|ClHMealc.KOH−−−−CH3CH=CH2

(ii) CH3CH2CH2Clalc.KOH−−−−CH3CH=CH2

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Solution

These reactions are the type of elimination reaction
Here reaction (i) is faster than reaction (ii).
MeC|ClHMealc.KOH−−−−CH3CH=CH2
In this reaction, the tertiary carbocation is formed.
The formed carbocation is most stable in the first case as two CH3 groups are stabilizing it
SO (i) is fast.

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