Among the solubility rules is the statement that carbonates, phosphates, borates, arsenates, and arsenites, except those of the ammonium ion and the alkali metals are insoluble.
A
1. K=[Ca2+][CO2−3],K>1, 2. K=1[Ba2+]3[PO3−4]2,K>1
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B
1. K=[Ca2+][CO2−3],K=1, 2. K=1[Ba2+]3[PO3−4]2,K<1
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C
1. K=[Ca2+][CO2−3],K>1, 2. K=1[Ba2+]3[PO3−4]2,K=1
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D
1. K=[Ca2+][CO2−3],K<1, 2. K=1[Ba2+]3[PO3−4]2,K>1
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Solution
The correct option is D 1. K=[Ca2+][CO2−3],K<1, 2. K=1[Ba2+]3[PO3−4]2,K>1 CaCO3(s)⇌Ca2+(aq)+CO2−3(aq) K=[Ca2+][CO2−3],K<1 3Ba2+(aq)+2PO3−4(aq)⇌Ba3(PO4)2(s) K=1[Ba2+]3[PO3−4]2,K>1