An alkyl bromide (A) forms Grignard reagent which on treatment with water, yields n-hexane. (A) On treatment with sodium forms 4,5-diethyloctane. (A) is:
A
CH3−(CH2)5−Br
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B
CH3−(CH2)3−CHBr−CH3
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C
CH3−(CH2)2−Br|CH−CH2−CH3
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D
CH3−(CH2)2−Br|CH−CH=CH2
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Solution
The correct option is CCH3−(CH2)2−Br|CH−CH2−CH3
Grignard reagent is a strong base and it is easily protonated to form alkane.
Alkyl bromide undergoes wurtz reaction to give symmetrical alkane.