An aqueous solution of a non-volatile solute boils at 100.17oC. At what temperature will the solution freeze? (Given:Kb=0.512Kkgmol−1 and Kf=1.86Kkgmol−1)
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Solution
We know that, △Tb=molality×Kb 0.17=molality×0.512 Molality of the solution =0.170.512m Let depression in freezing point be △Tf △Tf=molality×Kf =0.170.512×1.86=0.62oC Thus, the freezing point of the solution =0.00−0.62=−0.62oC