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Question

An aqueous solution of X is added slowly to an aqueous solution of Y as shown in List I. The variation in conductivity of theses reactions is given in List II. Match List I with List II and select the correct using the code given below the lists:

List-A
List-B
(P) (C2H5)3NX+CH2COOHY
(1) Conductivity decreases and then increases
(Q) KI(0.1M)X+AgNO3(0.01M)Y
(2) Conductivity decreases and then does not change much
(R) CH2COOX+KOHY(3) Conductivity increases and then does not change much
(S) NaOHX+HIY(4) Conductivity does not change much and then increases.

A
3, 4, 2, 1
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B
4, 3, 2, 1
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C
2, 3, 4, 1
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D
1, 4, 3, 2
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Solution

The correct option is C 3, 4, 2, 1
(P) (C2H5)3NX+CH2COOHY
(3) Since a weak base is added to weak acid, the conductivity
increases and then dos not change much.
(Q) KI(0.1M)X+AgNO3(0.01M)Y
(4) Since an strong electrolyte is added to strong electrolyte, the conductivity dos not change much and then increases.
(R) CH2COOX+KOHY
(2) Since a weak acid is added to strong base, the conductivity decreases and then does not change much.
(S) NaOHX+HIY
(1) Since a strong base is added to an acid, the conductivity decreases and then increases.

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