An element A in a compound ABD has oxidation number An-. It is oxidised by Cr2O−72 in acid medium. In the experiment 1.68×10−3 x moles ofK2Cr2O7 were used for 3.26×10−3 moles of ABD. The new oxidation number of A after oxidation is:
3-n
Equivalent ofCr2O−72 = Equivalent ofABD
1.68×10−3×6 =3.26×10−3×X
X =3
New oxidation no =3-n