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Question

An element (atomic mass = 100 g/mole) having BCC structure has an edge length of 400 pm. The density of the element is (no. of atoms in BCCZ=2).

A
2.144 g/cm3
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B
5.2 g/cm3
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C
7.289 g/cm3
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D
10.376 g/cm3
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Solution

The correct option is B 5.2 g/cm3
Mass of a unit cell =Z×MNA
Z is the number of atoms per unit cell which is 2 for BCC
M is the molar mass of the atom = 100 g/mol
NA is avagadro number
Volume of the unit cell =a3
Here, a is the edge length = 400 pm
Density of a unit cell is given by
ρ=Z×MNA×a3
i.e ρ=2×1006×1023×(400×1010)3 = 5.2 g/cm3

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