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Question

An experiment showed that a lead chloride solution is formed when 6.21 g of lead combines with 4.26 g of chlorine. What is the empirical formula of this chloride?

[Pb = 207; Cl = 35.5]

A
PbCl3
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B
PbCl2
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C
PbCl4
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D
PbCl
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Solution

The correct option is D PbCl4

Mass

Atomic weight

Relative no. of moles

Simplest ratio

Lead

6.21 g

207

6.21/207 = 0.03

0.03/0.03 = 1

Chlorine

4.26 g

35.5

4.26/35.5 = 0.12

0.12/0.03 = 4


Hence, empirical formula is PbCl4.

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