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Question

An ideal gas has molar heat capacity at constant pressure Cp=5R2. The gas is kept in a cylindrical vessel fitted with a piston which is free to move. Mass of the frictionless piston is 9 kg. Initial volume of the gas is 0.0027 m3 and cross-section area of the piston is 0.09 m2. The initial temperature of the gas is 300 K. Atmospheric pressure P0=1.05×105 N/m2. An amount of 2.5×104 J of heat energy is supplied to the gas such that piston move without acceleration, then

A
Initial pressure of the gas is 1.06×105 N/m2
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B
Work done by the gas is 1000 J
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C
Final pressure of the gas is 1.06×105 N/m2
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D
Work done by gas is 9.94×103 J
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Solution

The correct options are
A Initial pressure of the gas is 1.06×105 N/m2
C Final pressure of the gas is 1.06×105 N/m2
D Work done by gas is 9.94×103 J
PV=nRT(1)
Since, pressure of gas is balancing outside atmospheric pressure and pressure due to weight of piston.
Mass of piston is 9 kg and area of piston is 0.09 m2

So, P=P0+9g0.09

P=1.06×105 N/m2
So, Initial and final pressure of the gas is 1.06×105 N/m2

As mass of piston is not changed and piston is frictionless. So, process is isobaric.

Pf=P1=1.06×105 N/m2

dQ=n Cp dT(2)

or P2V2P1V1=n R dT(3)

(3) ÷ (2) P(V2V1)dQ=25

P(V2V1)=25×2.5×104

W=PΔV=104 J


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