The correct option is B The 2nd harmonic
An open pipe length l=33 cm=0.33 m
velocity of sound v=330 m/s
The fundamental frequency for open pipe ,λ=2l
⇒n=vλ=v2l
⇒n=3302×0.33
⇒n=500 Hz
In second harmonic frequency ,n=vl=3300.33
⇒n=1000 Hz
Final answer : (b)