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Question

An organic compound (A) with the molecular formula, (C7H8O) dissolves in NaOH and gives characteristics colour with neutral FeCl3. On treatment with bromine water, it gives a tribromo derivative, C7H5OBr3. The compound is:

A
p-cresol
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B
o-cresol
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C
m-cresol
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D
benzyl alcohol
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Solution

The correct option is C m-cresol
Reactivity of compound ‘A’ with NaOH and FeCl3 suggests (A) to be a phenol. The formation of a tribromo product suggests that o & p positions are vacant. So the CH3 group should be present at m-positons. Hence (A) is m-cresol.

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