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Question

An organic compound has C and H percentage in the ratio 6:1 by mass and C and O percentage in the ratio 3:4 by mass. The compound is:

A
HCHO
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B
CH3OH
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C
CH3CH2OH
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D
(COOH)2
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Solution

The correct option is A HCHO
An organic compound has C and H percentage in the ratio 6:1 by mass and C and O percentage in the ratio 3:4 by mass. Thus, the compound will contain 6 g of C for each g of H and 8 g of O. The atomic masses of C, H and O are 12 g/mol, 1 g/mol, 16 g/mol respectively.
The number of moles of C =6/g12 g/mol=0.5 mol.
The number of moles of H =1/g1 g/mol=1 mol.
The number of moles of O =8/g16 g/mol=0.5 mol.
The mole ratio C:H:O=0.5:1:0.5 =1:2:1
Hence, the compound is CH2O or HCHO

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