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Question

An organic compound neither reacts with neutral ferric chloride solution nor with Fehling's solution. It however, reacts with grignard reagent and gives positive iodoform test. The compound is:

A
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B
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C
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D
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Solution

The correct option is C
Analysing the given information, we found that compound gives haloform test positive. From the options, only (a) and (c) can fulfill this criteria because it has O||CCH3 and OH|CCH3 groups respectively. Since the asked compound does not react with neutral FeCl3 solution hence the correct option is (c). (a) contains a phenolic OH which reacts with neutral FeCl3 solution

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