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Question

An organisc compound, whose vapour density is 45, has the following percentage composition,
H = 2.22 % O = 71 . 19% and remaining carbon.

Calculate:
(a) its empirical formula, (b) its molecular formula.

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Solution

Element % at. mass atomic ratio simple ratio
C 26.59 12 26.5912=2.21 1
H 2.22 1 2.221=2.22 1
O 71.19 16 71.1916=4.44 2


(a) its empirical formula =CHO subscript 2
(b)empirical formula mass = 45
vapour density = 45
so molecular mass=VD × 2 = 90
so molecular formula C subscript 2 H subscript 2 O subscript 4


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