An unknown mixture contains one or two of the following :
CaCO3,BaCl2,AgNO3,Na2SO4,ZnSO4 and NaOH.
The mixture is completely soluble in water and solution gives pink colour With phenolphthalein. When dilute hydrochloric acid is gradually added to the solution, a precipitate is formed which dissolves with further addition of the acid.
The white precipitate is_______.