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Question

Analysis of vitamin C shows that it contains 40.92% carbon by mass, 4.58% hydrogen and 54.50% oxygen. Determine the empirical formula of vitamin C.

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Solution

Vitamin C contains 40.92% carbon by mass, 4.58% hydrogen and 54.50% oxygen.

100 g of vitamin C will contain 40.92 g C, 4.58 g, H and 54.50 g O.
Atomic masses of C, H and O are 12 g/mol, 1 g/mol and 16 g/mol respectively.

Number of moles of C=40.92 g12 g/mol=3.4 mol.

Number of moles of H=4.58 g1 g/mol=4.58 mol.

Number of moles of O=54.50 g16 g/mol=3.40 mol.

Mole ratio of C : H : O = 3.4 : 4.58 : 3.4 = 3 : 4 : 3

Empirical formula of vitamin C is C3H4O3.

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